Kinetics of the Uninhibited and Resorcinol Inhibited CoO Catalysed Autoxidation of Sulfur (IV) in Alkaline Heterogeneous Medium
Keywords:
Autoxidation of Sulfur, CoO, Uninhibited, Alkaline Heterogenous Medium
Abstract
The kinetics of resorcinol inhibited CoO catalysed S(IV) autoxidation in the pH range 7.50 to 8.50 medium have been investigated and a rate law & free radical mechanism have been proposed based on the observed results and inhibition parameters. In all situations, the reaction's order and rate constants were calculated, meanwhile, the reaction was determined to be first-order. The impact of various temperatures & pH levels were explored also. We reported resorcinol as a significant inhibitor for SO2 autoxidation in the pH range of 7.50 to 8.80. The Arrhenius equation was used to get the value of apparent activation energy (Ea) (K= A.e-Ea/RT).
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References
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4. Gupta K.S, Jain U, Singh A, Mehta RK, Manoj SV, Prasad DSN, Sharma A, Parashar P, Bansal SP. Kinetics and mechanism of the osmium(VIII)-catalysed autoxidation of aqueous sulfur dioxide in acidic and alkaline media. Journal of the Indian Chemical Society .2004;81(12):1083-92.
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8. Bhargava R, Prasad DS, Rani A, Bhargava P, Jain U, Gupta KS. Kinetics of autoxidation of aqueous sulfur dioxide in suspensions of nickel (III) oxide. Transition Metal Chemistry. 1992 Jun1;17(3):238-41.
9. Prasad DSN, Rani A, Gupta KS. Surface-catalyzed autoxidation of sulfur (IV) in aqueous silica and copper (II) oxide suspensions. Environmental science& technology. 1992 Jul;26(7):1361-8.
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11. Manoj SV, Mishra CD, Sharma M, Rani A, Jain R, Bansal SP, Gupta KS. Iron, manganese, and copper concentrations in wet precipitations and kinetics of the oxidation of SO2 in rainwater at two urban sites, Jaipur and Kota, in western India. Atmospheric Environment. 2000 Aug 2;34(26):4479-86.
12. Ghosh MK, Rajput SK. Kinetics and Mechanism of Lanthanum (III) Catalysed Oxidation of Rwd3fD-ribose by Cerium (IV) in Aqueous Acidic Medium. Asian Journal of Research in Chemistry. 2012;5(10):1271-7.
13. Manoj, S. V., Singh, R., Sharma, M., & Gupta, K. S. (2000). Kinetics and mechanism of heterogeneous cadmium sulfide and homogeneous manganese (II) catalysed oxidation of sulfur (IV) by dioxygen in acetate buffered medium.
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17. Connick, R. E., & Zhang, Y. X. (1996). Kinetics and mechanism of the oxidation of HSO3-by O2. 2. the manganese (II)-catalyzed reaction. Inorganic Chemistry, 35(16), 4613-4621.
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22. Prasad, D. S. N., Rani, A., Madnawat, P. V. S., Bhargava, R., & Gupta, K. S. (1991). Kinetics of surface-catalyzed oxidation of sulfur (IV) by dioxygen in aqueous suspensions of cobalt (II) oxide. Journal of molecular catalysis, 69(3), 393-405.Barker, J. R. (1995). Progress and problems in atmospheric chemistry (Vol. 3). World Scientific.
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24. Alyea, H. N., & Bäckström, H. L. (1929). The inhibitive action of alcohols on the oxidation of sodium sulfite. Journal of the American Chemical Society, 51(1), 90-109.
25. Hussain, F., Begam, S., Sharma, A. K., & Prasad, D. S. N. (2018). Effect of isopropyl alcohol on the autoxidation of S (IV) catalyzed by Co2O3 in alkaline medium. Bull. Pure Appl. Sci. 37 (1): 9, 18.
26. Ziajka J, Pasiuk-Bronikowska W (2003) Autoxidation of sulfur dioxide in the presence of alcohols under conditions related to the tropospheric aqueous phase. Atmos Environ 37:3913–3922.
27. Ghosh, M. K., & Rajput, S. K. (2012). Kinetics and Mechanism of Lanthanum (III) Catalysed Oxidation of D-ribose by Cerium (IV) in Aqueous Acidic Medium. Asian Journal of Research in Chemistry, 5(10), 1271-1277.
28. Wang, L., Xing, L., Liu, J., Qi, T., Zhang, S., Ma, Y., & Ning, P. (2021). Construction of lattice-confined Co-MCM-48 for boosting sulfite oxidation in wet desulfuration. Chemical Engineering Journal, 407, 127210.
29. Meena, V., Dayal, Y., Saxena, D., Rani, A., Chandel, C.P.& Gupta, K.S., (2016). The influence of diesel-truck exhaust particles on the kinetics of the atmospheric oxidation of dissolved sulfur dioxide by oxygen. Environ SciPollut Res., 23(17):17380-92.
30. HUIE, R. E., & SIECK, L. W. (1999). 3 SO, Radical Monoanions—Reactions. S-Centered Radicals, 1, 63.
31. Liu, J., Wang, H., Wang, L., Xing, L., Zhang, S., Xiao, H., & Ma, Y. (2019). The defect-engineered cobalt-based solid catalyst for high-efficiency oxidation of sulfite. Chemical Engineering Science, 197, 1-10.
32. Wilkosz, I., & Mainka, A. (2008). Mn (II)-catalysed S (IV) oxidation and its inhibition by acetic acid in acidic aqueous solutions. Journal of atmospheric chemistry, 60(1), 1-17.
33. Schöne, L., Schindelka, J., Szeremeta, E., Schaefer, T., Hoffmann, D., Rudzinski, K. J., ... & Herrmann, H. (2014). Atmospheric aqueous phase radical chemistry of the isoprene oxidation products methacrolein, methyl vinyl ketone, methacrylic acid, and acrylic acid–kinetics and product studies. Physical Chemistry Chemical Physics, 16(13), 6257-6272.
34. Podkrajšek, B., Grgić, I., Turšič, J., & Berčič, G. (2006). Influence of atmospheric carboxylic acids on catalytic oxidation of sulfur (IV). Journal of Atmospheric Chemistry, 54(2), 103-120...
35. Sharma, A. K., Sharma, R., & Prasad, D. S. N. (2017). Kinetics of isoamyl alcohol and aniline inhibited uncatalysed and Ag (I) catalysed autoxidation of S (IV) in an acidic medium. Asian Journal of Research in Chemistry, 10(3), 251-258.
36. Hussain, F. A. I. Y. A. Z., Begam, S. A. M. E. E. N. A., Sharma, A. K., & Prasad, D. S. N. (2018). Co2O3 catalyzed oxidation of SO2 in aqueous solution differing effect of benzamide in alkaline medium. Chem. Sci. Trans, 7(4), 600-609.
37. Sharma, A. K., Parasher, P., Sharma, R., & SN Prasad, D. (2017). Ag (I) Catalyzed Oxidation of SO2 in Aqueous Solution Differing Effect of Benzoate Ions in Acidic Medium. Current Physical Chemistry, 7(4), 338-347.
38. Sharma, A. K., Sharma, R., Prasad, D. S. N., & Parashar, P. (2016). The Inhibitive action of Aniline on the autoxidation of sodium sulfite in acidic medium. J. Anal. Pharm. Res, 17(5), 14-23.
39. Sharma, A. K., Sharma, R., & Prasad, D. S. N. (2017). The effect of atmospheric aromatic amides on the Ag (I) catalyzed S (IV) autoxidation in an aqueous solution. the Experiment, 40(1), 2354-2363.
40. Sharma, A. K., Sharma, R., & Prasad, D. S. N. (2017). Role of organics in atmospheric catalytic autoxidation of aqueous sulfur dioxide in acidic medium. Malaysian Journal of Chemistry, 19(1), 1-12.23.
41. L. Wang, Y. Ma, W. Zhang, Q., Li, Y., Zhao, Z. Zhang, J. Hazard. Mater,2013, 258-259
42. Dhayal, Y., Chandel, C. P. S., & Gupta, K. S. (2014). Role of some organic inhibitors on the oxidation of dissolved sulfur dioxide by oxygen in rainwater medium. Environmental Science and Pollution Research, 21(5), 3474-3483.
43. Meena, V. K., Dhayal, Y., Saxena, D., Rani, A., Chandel, C. P., & Gupta, K. S. (2016). The influence of diesel—truck exhaust particles on the kinetics of the atmospheric oxidation of dissolved sulfur dioxide by oxygen. Environmental Science and Pollution Research, 23(17), 17380-17392.
44. Prasad, D.S.N., Rani, A., Madnavat, P.V.S., Bhargava, R. &Gupta, K.S.(1991). Kinetics of surface catalyzed oxidation of sulfur(IV) by dioxygen in aqueous suspensions of cobalt(II) oxide.J. Mol. Catal., 69:395-405.
45. Begam S, Hussain F, Singh J, Sharma AK, Prasad DS. Kinetics of sodium sulfite oxidation catalyzed by Co2O3 and inhibited by ethylene glycol. Asian Journal of Research in Chemistry. 2018 Jun 30;11(3):610-6
46. Sharma, A.K., Sharma, R.&Prasad, D.S.N.(2018). Effect of Aliphatic Mono Carboxylic acids and alcohols on Ag(I) Catalysed oxidation of SO2 in aqueous solution, J. Mat. Env. Sci.,9(6): 1829-1837.
47. Gupta, K.S., Singh, R., Saxena, D., Manoj, S.V.& Sharma, M.,(1999). Role of manganese dioxide in the autoxidation of sulfur (IV) in oxic and anoxic suspensions. Ind. J .Chem.,38A:1129-1138.
48. Mudgal, P. K., Sharma, A. K., Mishra, C. D., Bansal, S. P., & Gupta, K. S. (2008). Kinetics of ammonia and ammonium ion inhibition of the atmospheric oxidation of aqueous sulfur dioxide by oxygen. Journal of atmospheric chemistry, 61(1), 31-55.
49. Sharma, A.K., Sharma, R., Prasad, D.S.N. &Parashar, P.(2016). The Inhibitive action of Aniline on the autoxidation of sodium sulfite in acidic medium.J.Anal.Pharm.Res.,17(5):14-23.
50. Gupta, K.S.(2012).Aqueous phase atmospheric oxidation of sulfur dioxide by oxygen: role of trace atmospheric constituents metals, volatile organic compounds, and ammonia J.Indian Chem. Soc.,89: 713- 724.
2. Hemann H (2003) Kinetics of aqueous–phase reactions relevant to atmospheric chemistry. Chem Rev 103:4691-4716.
3. Gupta, K.S.(2012).Aqueous phase atmospheric oxidation of sulfur dioxide by oxygen: role of trace atmospheric constituents metals, volatile organic compounds and ammonia J.Indianchem. Soc.,89: 713- 724.
4. Gupta K.S, Jain U, Singh A, Mehta RK, Manoj SV, Prasad DSN, Sharma A, Parashar P, Bansal SP. Kinetics and mechanism of the osmium(VIII)-catalysed autoxidation of aqueous sulfur dioxide in acidic and alkaline media. Journal of the Indian Chemical Society .2004;81(12):1083-92.
5. Acker K, Moller D, WieprechiW, Auel R, Kalass D, and Tscherwenka W, 2001, Nitrous and nitric acid measurements inside and outside of clouds at mt. Brocken Water Air and Soil Pollution,130, 331-336.
6. Berresheim, H., & Jaeschke, W. (1986). Study of metal aerosol systems as a sink for atmospheric SO2. Journal of atmospheric chemistry, 4(3), 311-334.
7. Prasad DSN, Mehta RK, Parashar P, Madnawat PV, Rani A, Singh U, Manoj SV, Bansal SP, Gupta KS. Kinetics of surface-catalyzed autoxidation of aqueous sulfur dioxide in cobalt (III) oxide suspensions. Journal of the Indian Chemical Society. 2003;80(4):391-4.
8. Bhargava R, Prasad DS, Rani A, Bhargava P, Jain U, Gupta KS. Kinetics of autoxidation of aqueous sulfur dioxide in suspensions of nickel (III) oxide. Transition Metal Chemistry. 1992 Jun1;17(3):238-41.
9. Prasad DSN, Rani A, Gupta KS. Surface-catalyzed autoxidation of sulfur (IV) in aqueous silica and copper (II) oxide suspensions. Environmental science& technology. 1992 Jul;26(7):1361-8.
10. Gupta KS, Singh R, Saxena D, Manoj SV, Sharma M. Role of manganese dioxide in the autoxidation of sulfur (IV) in oxic and anoxic suspensions Ind. J. Chem.1999, 38A,1129- 1138.
11. Manoj SV, Mishra CD, Sharma M, Rani A, Jain R, Bansal SP, Gupta KS. Iron, manganese, and copper concentrations in wet precipitations and kinetics of the oxidation of SO2 in rainwater at two urban sites, Jaipur and Kota, in western India. Atmospheric Environment. 2000 Aug 2;34(26):4479-86.
12. Ghosh MK, Rajput SK. Kinetics and Mechanism of Lanthanum (III) Catalysed Oxidation of Rwd3fD-ribose by Cerium (IV) in Aqueous Acidic Medium. Asian Journal of Research in Chemistry. 2012;5(10):1271-7.
13. Manoj, S. V., Singh, R., Sharma, M., & Gupta, K. S. (2000). Kinetics and mechanism of heterogeneous cadmium sulfide and homogeneous manganese (II) catalysed oxidation of sulfur (IV) by dioxygen in acetate buffered medium.
14. Bäckström, H. L. (1934). Der Kettenmechanismus bei der Autoxydation von Aldehyden. Zeitschrift für physikalische Chemie, 25(1), 99-121.
15. Warneck, P., & Ziajka, J. (1995). Reaction Mechanism of the Iron (III)‐Catalyzed Autoxidation of Bisulfite in Aqueous Solution: Steady State Description for Benzene as Radical Scavenger. Berichte der Bunsengesellschaft für physikalische Chemie, 99(1), 59-65.
16. Ziajka, J., & Pasiuk-Bronikowska, W. (2003). Autoxidation of sulfur dioxide in the presence of alcohols under conditions related to the tropospheric aqueous phase. Atmospheric Environment, 37(28), 3913-3922.
17. Connick, R. E., & Zhang, Y. X. (1996). Kinetics and mechanism of the oxidation of HSO3-by O2. 2. the manganese (II)-catalyzed reaction. Inorganic Chemistry, 35(16), 4613-4621.
18. Connick, R. E., Zhang, Y. X., Lee, S., Adamic, R., & Chieng, P. (1995). Kinetics and mechanism of the oxidation of HSO3-by O2. 1. the uncatalyzed reaction. Inorganic Chemistry, 34(18), 4543-4553.
19. Kuo, D. T., Kirk, D. W., & Jia, C. Q. (2006). The chemistry of aqueous S (IV)-Fe-O2 system: state of the art. Journal of Sulfur Chemistry, 27(5), 461-530.
20. Brandt, C., & Van Eldik, R. (1995). Transition metal-catalyzed oxidation of sulfur (IV) oxides. Atmospheric-relevant processes and mechanisms. Chemical Reviews, 95(1), 119-190.
21. Grgić, I., Podkrajšek, B., Barzaghi, P., & Herrmann, H. (2007). Scavenging of SO4− radical anions by mono-and dicarboxylic acids in the Mn (II)-catalyzed S (IV) oxidation in aqueous solution. Atmospheric Environment, 41(39), 9187-9194.
22. Prasad, D. S. N., Rani, A., Madnawat, P. V. S., Bhargava, R., & Gupta, K. S. (1991). Kinetics of surface-catalyzed oxidation of sulfur (IV) by dioxygen in aqueous suspensions of cobalt (II) oxide. Journal of molecular catalysis, 69(3), 393-405.Barker, J. R. (1995). Progress and problems in atmospheric chemistry (Vol. 3). World Scientific.
23. Bigelow S. L.,1988, Catalytic effects in the oxidation of sodium sulfite by air oxygen , Zeitschriftfuerphysikalische Chemie,26,493-532.
24. Alyea, H. N., & Bäckström, H. L. (1929). The inhibitive action of alcohols on the oxidation of sodium sulfite. Journal of the American Chemical Society, 51(1), 90-109.
25. Hussain, F., Begam, S., Sharma, A. K., & Prasad, D. S. N. (2018). Effect of isopropyl alcohol on the autoxidation of S (IV) catalyzed by Co2O3 in alkaline medium. Bull. Pure Appl. Sci. 37 (1): 9, 18.
26. Ziajka J, Pasiuk-Bronikowska W (2003) Autoxidation of sulfur dioxide in the presence of alcohols under conditions related to the tropospheric aqueous phase. Atmos Environ 37:3913–3922.
27. Ghosh, M. K., & Rajput, S. K. (2012). Kinetics and Mechanism of Lanthanum (III) Catalysed Oxidation of D-ribose by Cerium (IV) in Aqueous Acidic Medium. Asian Journal of Research in Chemistry, 5(10), 1271-1277.
28. Wang, L., Xing, L., Liu, J., Qi, T., Zhang, S., Ma, Y., & Ning, P. (2021). Construction of lattice-confined Co-MCM-48 for boosting sulfite oxidation in wet desulfuration. Chemical Engineering Journal, 407, 127210.
29. Meena, V., Dayal, Y., Saxena, D., Rani, A., Chandel, C.P.& Gupta, K.S., (2016). The influence of diesel-truck exhaust particles on the kinetics of the atmospheric oxidation of dissolved sulfur dioxide by oxygen. Environ SciPollut Res., 23(17):17380-92.
30. HUIE, R. E., & SIECK, L. W. (1999). 3 SO, Radical Monoanions—Reactions. S-Centered Radicals, 1, 63.
31. Liu, J., Wang, H., Wang, L., Xing, L., Zhang, S., Xiao, H., & Ma, Y. (2019). The defect-engineered cobalt-based solid catalyst for high-efficiency oxidation of sulfite. Chemical Engineering Science, 197, 1-10.
32. Wilkosz, I., & Mainka, A. (2008). Mn (II)-catalysed S (IV) oxidation and its inhibition by acetic acid in acidic aqueous solutions. Journal of atmospheric chemistry, 60(1), 1-17.
33. Schöne, L., Schindelka, J., Szeremeta, E., Schaefer, T., Hoffmann, D., Rudzinski, K. J., ... & Herrmann, H. (2014). Atmospheric aqueous phase radical chemistry of the isoprene oxidation products methacrolein, methyl vinyl ketone, methacrylic acid, and acrylic acid–kinetics and product studies. Physical Chemistry Chemical Physics, 16(13), 6257-6272.
34. Podkrajšek, B., Grgić, I., Turšič, J., & Berčič, G. (2006). Influence of atmospheric carboxylic acids on catalytic oxidation of sulfur (IV). Journal of Atmospheric Chemistry, 54(2), 103-120...
35. Sharma, A. K., Sharma, R., & Prasad, D. S. N. (2017). Kinetics of isoamyl alcohol and aniline inhibited uncatalysed and Ag (I) catalysed autoxidation of S (IV) in an acidic medium. Asian Journal of Research in Chemistry, 10(3), 251-258.
36. Hussain, F. A. I. Y. A. Z., Begam, S. A. M. E. E. N. A., Sharma, A. K., & Prasad, D. S. N. (2018). Co2O3 catalyzed oxidation of SO2 in aqueous solution differing effect of benzamide in alkaline medium. Chem. Sci. Trans, 7(4), 600-609.
37. Sharma, A. K., Parasher, P., Sharma, R., & SN Prasad, D. (2017). Ag (I) Catalyzed Oxidation of SO2 in Aqueous Solution Differing Effect of Benzoate Ions in Acidic Medium. Current Physical Chemistry, 7(4), 338-347.
38. Sharma, A. K., Sharma, R., Prasad, D. S. N., & Parashar, P. (2016). The Inhibitive action of Aniline on the autoxidation of sodium sulfite in acidic medium. J. Anal. Pharm. Res, 17(5), 14-23.
39. Sharma, A. K., Sharma, R., & Prasad, D. S. N. (2017). The effect of atmospheric aromatic amides on the Ag (I) catalyzed S (IV) autoxidation in an aqueous solution. the Experiment, 40(1), 2354-2363.
40. Sharma, A. K., Sharma, R., & Prasad, D. S. N. (2017). Role of organics in atmospheric catalytic autoxidation of aqueous sulfur dioxide in acidic medium. Malaysian Journal of Chemistry, 19(1), 1-12.23.
41. L. Wang, Y. Ma, W. Zhang, Q., Li, Y., Zhao, Z. Zhang, J. Hazard. Mater,2013, 258-259
42. Dhayal, Y., Chandel, C. P. S., & Gupta, K. S. (2014). Role of some organic inhibitors on the oxidation of dissolved sulfur dioxide by oxygen in rainwater medium. Environmental Science and Pollution Research, 21(5), 3474-3483.
43. Meena, V. K., Dhayal, Y., Saxena, D., Rani, A., Chandel, C. P., & Gupta, K. S. (2016). The influence of diesel—truck exhaust particles on the kinetics of the atmospheric oxidation of dissolved sulfur dioxide by oxygen. Environmental Science and Pollution Research, 23(17), 17380-17392.
44. Prasad, D.S.N., Rani, A., Madnavat, P.V.S., Bhargava, R. &Gupta, K.S.(1991). Kinetics of surface catalyzed oxidation of sulfur(IV) by dioxygen in aqueous suspensions of cobalt(II) oxide.J. Mol. Catal., 69:395-405.
45. Begam S, Hussain F, Singh J, Sharma AK, Prasad DS. Kinetics of sodium sulfite oxidation catalyzed by Co2O3 and inhibited by ethylene glycol. Asian Journal of Research in Chemistry. 2018 Jun 30;11(3):610-6
46. Sharma, A.K., Sharma, R.&Prasad, D.S.N.(2018). Effect of Aliphatic Mono Carboxylic acids and alcohols on Ag(I) Catalysed oxidation of SO2 in aqueous solution, J. Mat. Env. Sci.,9(6): 1829-1837.
47. Gupta, K.S., Singh, R., Saxena, D., Manoj, S.V.& Sharma, M.,(1999). Role of manganese dioxide in the autoxidation of sulfur (IV) in oxic and anoxic suspensions. Ind. J .Chem.,38A:1129-1138.
48. Mudgal, P. K., Sharma, A. K., Mishra, C. D., Bansal, S. P., & Gupta, K. S. (2008). Kinetics of ammonia and ammonium ion inhibition of the atmospheric oxidation of aqueous sulfur dioxide by oxygen. Journal of atmospheric chemistry, 61(1), 31-55.
49. Sharma, A.K., Sharma, R., Prasad, D.S.N. &Parashar, P.(2016). The Inhibitive action of Aniline on the autoxidation of sodium sulfite in acidic medium.J.Anal.Pharm.Res.,17(5):14-23.
50. Gupta, K.S.(2012).Aqueous phase atmospheric oxidation of sulfur dioxide by oxygen: role of trace atmospheric constituents metals, volatile organic compounds, and ammonia J.Indian Chem. Soc.,89: 713- 724.
Published
2022-09-08
How to Cite
Kumar, M., Yadav, M. B., Khinchi, S., & Prasad, D. (2022). Kinetics of the Uninhibited and Resorcinol Inhibited CoO Catalysed Autoxidation of Sulfur (IV) in Alkaline Heterogeneous Medium. Central Asian Journal of Theoretical and Applied Science, 3(9), 1-15. https://doi.org/10.17605/OSF.IO/8FYUN
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